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Chemistry: Bonding Structures

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Chemistry: Bonding Structures
« on: September 08, 2014, 10:22:30 AM »
Bonding Structures  In the previous chapter, we studied that noble gases are  stable and unreactive because they have a full energy shells. All other elements are seeking this property too. They all want to have full outer most  energy shells; this is why reactions take place. For example if an atom has 6  electrons in its outer most shell, it tries to gain two electrons from other  atoms to complete the shell with 8 electrons. We have two types of bonds, ionic and covalent bonds.
 Ionic Bonding:  This type of bonding is based on the electrostatic force of attraction between the ions in the molecule. For example, when sodium, which is  in group one and has one electron in its outer most shell, reacts with  chlorine, which is in group 7 and has 7 electrons in its outer most shell, the sodium  gets rid of the only electron in its outer shell, thus the sodium atom will  have its second most outer shell which is full become its most outer shell  forming a positive ion. The electron which is lost by the sodium atom is gained  by the chlorine atom to 8 electrons, thus filling its outer most shell and  becoming a negative ion. This electron transfer causes the electrostatic force  of attraction which holds the oppositely charged ions together in a molecule.  When an atom becomes an ion, it gets the properties of the noble gas which is  nearest to it in the periodic table. Ionic bonds are only formed between metals  and non-metals.
Formulae of Ionic Compounds:  To find the formula for an ionic compound, we use a method similar to cross multiplication. We multiply the valency (valency is the number of electrons an atom loses or gains to form an  ion) to the other atom as shown below:
Properties of Ionic Compounds:
  • Hard solids at room temperature,
  • High melting and boiling points because of strong attraction  forces,
  • When solid they are electrical insulators but conduct  electricity when molten or aqueous,
  • Water soluble.
 
 Covalent Bonding: This type of bonding occurs between non-metals only. In  order to obtain a full outer most energy shell, the atoms tend to share the electrons of their outer most energy shell, some or all of them.
 Example #1: A hydrogen molecule:  Each hydrogen atoms has 1 electron in its outer most shell. When it bonds covalently, it shares this electron with another hydrogen atom,  which also shares its only valence electron. This causes each atom in the  molecule to have 2 electrons in its outer most shell, which is also the 1st and  only shell; this means it is holding the maximum number of electrons making it  stable.
If two atoms each share one electron, it is called a single covalent bond, if each shares two electrons; it is a double covalent bond. The  single covalent bond above can be represented by H - H.
 A double covalent bond between two carbon atoms can be  represented b C = C.
 
Example #2: Methane molecule:  Each carbon atom has 4 valence electrons, this means it can  bond with 4 hydrogen atoms (1 valence electron) covalently as shown on the right.
This molecule can also be represented like this:
 
 
 Types of Covalent Structures: There are two types of covalent structures:
 
  • Simple Molecular Structure
  • Giant Molecular Structure
Simple Molecular Structure: They are simple and contain only a few atoms in one molecule. Covalent bonds between the atoms within a molecule (intermolecular bonds) are strong but they have weak bonds between molecules (intermolecular bonds). These forces increase as the size of the molecule increases.
  Giant Molecular Structure: They are also known as macromolecular structures. One molecule contains hundreds of thousands of atoms. They have extremely strong bonds between the atoms (intermolecular bonds).
 
 Properties of Covalent Compounds:
  • Simple molecular structures are usually gases or liquids and sometimes solids with low melting points; this is because of weak forces of  attraction between the molecules which can be broken easily.
  • Giant molecular structures have very high melting points because  the whole structure is held together with very strong covalent bonds.
  • Most of them do not conduct electricity
  • Most of them are insoluble in water
 
 Allotropes of Carbon:  What are allotropes?  When an element exists in several physical forms of the same state, it is said to exhibit allotropy. Each form of this element is an allotrope. Lots of elements exhibit allotropy. Carbon has two very popular  allotropes, diamond and graphite. Diamond and graphite are both made of carbon  only. However, they look very different and have different physical properties.  They are both giant molecular structures.
 Diamond:
In diamond’s structure, each carbon atom is covalently  bonded to four other carbon atoms by very strong bonds forming a 3D tetrahedral  shape.
 The physical properties of diamond:
  • Has a very high melting point (almost 4000°C). Very strong carbon-carbon covalent bonds have to be broken throughout the structure before melting occurs,
  • Is very hard. This is again due to the need to break very strong covalent bonds operating in 3-dimensions,
  • Doesn't conduct electricity. All the electrons are held tightly between the atoms, and aren't free to move,
  • Is insoluble in water and organic solvents. There are no possible attractions
which could occur between solvent molecules and carbon atoms which could outweigh the attractions between the covalently bound carbon atoms.
 
Graphite:
In the graphite structure, each carbon atom is strongly  bonded covalently to three other carbon atoms forming layers of linked  hexagons. Each layer acts as a molecule, the intermolecular forces between the  layers is very weak allowing layers to slide over each other. This makes  graphite a good lubricant.
 The physical properties of graphite: 
  • Has a high melting point, similar to that of diamond. In order   to melt graphite, it isn't enough to loosen one sheet from another.  You   have to break the covalent bonding throughout the whole structure,
  • Has a soft, slippery feel, and is used in pencils and as a dry   lubricant for things like locks. You can think of graphite rather like a   pack of cards - each card is strong, but the cards will slide over each   other, or even fall off the pack altogether.  When you use a pencil,   sheets are rubbed off and stick to the paper,
  • Has a lower density than diamond.  This is because of the relatively large amount of space that is "wasted" between the sheets,
  • Is insoluble in water and organic solvents - for the same reason   that diamond is insoluble.  Attractions between solvent molecules and   carbon atoms will never be strong enough to overcome the strong covalent   bonds in graphite,
  • Conducts electricity.  The delocalised electrons are free to move   throughout the sheets.  If a piece of graphite is connected into a   circuit, electrons can fall off one end of the sheet and be replaced   with new ones at the other end.
Metallic Structures:
Pure metals have a very unique structure. Each atom lets go  of the valence electrons and become a positive ion. These electrons altogether  form a sea of delocalized electrons.
Since the electrons are negatively charged  and the ions are positively charged, an electrostatic force of attraction is  formed between the sea of delocalized electrons and layers of positive ions.
The metallic lattice is the regular arrangement of positive  ions embedded in a sea of delocalized electrons.
The metallic bond is the electrostatic force of attraction between the layers of positive ions and the sea of delocalized electrons.
Properties of metals:
  • Malleable and ductile: Layers of positive ions are able to slide over each other,  the shape changes without breaking.
  • Conducts electricity: Sea of delocalized electrons is present to move freely  around the structure and carry the charge.
  • High melting and boiling points: Electrostatic forces of attraction between the ions and  electrons are very strong, lots of energy is needed to break them.
Alloys:  An alloy is a mixture of metals or metals and non-metals. Sometimes, and alloy is better than a metal because they have better properties. They are harder, more resistant to corrosion and have a more attractive appearance than the metals they are formed of.
Alloys are harder than metals because they have different  sized atoms which prevent the layers from sliding over each other.
And alloy is made by heating the metals or metals and  non-metals together until they all melt, and leaving them to cool mixed.
Examples of alloys and their content:
 
  • Brass: Copper-Zinc,
  • Bronze: Copper-Tin,
  • Steel: Iron-Carbon,
  • Stainless Steel: Iron-Carbon-Chromium-Nickel.

 

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